Drew Van Acker
𝘢𝘴
Matthew van der Woodsen
"The Other Golden Boy"

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Leighton Meester
𝘢𝘴
Blair Waldorf
"Queen B"

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Blake Lively
𝘢𝘴
Serena van der Woodsen
"It Girl"

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Chace Crawford
𝘢𝘴
Nate Archibald
"Golden Boy"

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Ed Westwick
𝘢𝘴
Chuck Bass
"People like me don't write books, we're written about"

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Penn Badgley
𝘢𝘴
Dan Humphrey
"Lonely Boy"

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and
Adam Brody
as
"The Best Friend"
Ace Woods (created by Biggirl568 )

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Lily Colins 
𝘢𝘴
Emily Cooper

(will be introduced in season two) 

and the rest of the cast