Shmi Skywalker: Anakin's beloved mother
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Obi-Wan Kenobi: Anakin's master, brotherly friend, and father figure
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Padme Amidala/Naberrie: Anakin's wife and love of his life
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Sheev Palpatine: Anakin's mentor
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Ahsoka Tano: Anakin's Padawan and younger sister figure
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Naomi Koda: Anakin's childhood friend
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Ellie Naberrie: Anakin's foster daughter
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Anastasia Skywalker: Anakin's foster sister
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Request other canon characters if you wish!

Any fan-made characters that you have who are canon compliant you may request to have a relationship with Anakin here and we can discuss the details.