The Girl Squad

Alona Tal as Jo Harvelle | the hunter

Rachel Miner as Meg Masters | the demon

Felicia Day as Charlie Bradbury | the hacker

Adrianne Palicki as Jessica Moore | the college girl

Team Free Will

Misha Collins as Castiel | an angel of the lord

Jared Padalecki as Sam Winchester | the bookworm

Jensen Ackles as Dean Winchester | the fighter

The Wild Cards

special appearances by 

Mark Sheppard as Crowley | the king of hell

Kim Rhodes as Jody Mills | the sheriff

Kathryn Newton as Claire Novak | the wayward daughter

and Katherine Radeem as Alex Jones | the wayward sister

with a very special appearance by a mystery character 

(sorry, folks, gotta keep some things secret here)