Capricorn- Nick Fury
Taurus- Hulk
Virgo- Maria Hill (S.H.I.E.L.D agent)
Aquarius- Agent Phil Coulson
Gemini- Loki
Libra- Spiderman (not from Avengers movie)
Pisces- Black Widow
Cancer- Iron man
Scorpio- Captain America
Aries- Superman (not from Avengers movie)
Leo- Thor
Sagittarius- Hawkeye